We usually measure or convert the watts into amps of solar panels to figure out how much current (amps) is being stored in the battery. Or we measure the amperage of the solar panel output to select the wire sizefrom solar panels. [pdf]
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For lithium batteries, simultaneous charging and discharging is possible due to their advanced chemistry. These batteries use a mechanism called “power-sharing” that allows them to operate efficiently while performing both functions. [pdf]
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